23 Augustus 2025
| 18:30 |
US Sassuolo Calcio 
0 - 2
SSC Napoli 
|
30 Augustus 2025
| 20:45 |
SSC Napoli
1 - 0
Cagliari Calcio 
|
13 September 2025
| 20:45 |
ACF Fiorentina 
1 - 3
SSC Napoli
|
18 September 2025
| 21:00 |
Manchester City FC 
2 - 0
SSC Napoli
|
22 September 2025
| 20:45 |
SSC Napoli
3 - 2
Pisa SC 
|
28 September 2025
| 20:45 |
AC Milan 
2 - 1
SSC Napoli
|
01 Oktober 2025
| 21:00 |
SSC Napoli
2 - 1
Sporting CP 
|
05 Oktober 2025
| 18:00 |
SSC Napoli
2 - 1
Genoa CFC 
|
18 Oktober 2025
| 18:00 |
Torino FC 
1 - 0
SSC Napoli
|
21 Oktober 2025
| 21:00 |
PSV 
6 - 2
SSC Napoli
|
25 Oktober 2025
| 18:00 |
SSC Napoli
3 - 1
FC Internazionale Milano 
|