15 Augustus 2025
| 21:30 |
Villarreal CF 
2 - 0
Real Oviedo 
|
24 Augustus 2025
| 19:30 |
Villarreal CF
5 - 0
Girona FC 
|
31 Augustus 2025
| 17:00 |
RC Celta de Vigo 
1 - 1
Villarreal CF
|
13 September 2025
| 21:00 |
Club Atlético de Madrid 
2 - 0
Villarreal CF
|
16 September 2025
| 21:00 |
Tottenham Hotspur FC 
1 - 0
Villarreal CF
|
20 September 2025
| 18:30 |
Villarreal CF
2 - 1
CA Osasuna 
|
23 September 2025
| 21:30 |
Sevilla FC 
1 - 2
Villarreal CF
|
27 September 2025
| 21:00 |
Villarreal CF
1 - 0
Athletic Club 
|
01 Oktober 2025
| 21:00 |
Villarreal CF
2 - 2
Juventus FC 
|
04 Oktober 2025
| 21:00 |
Real Madrid CF 
3 - 1
Villarreal CF
|
18 Oktober 2025
| 18:30 |
Villarreal CF
2 - 2
Real Betis Balompié 
|
21 Oktober 2025
| 21:00 |
Villarreal CF
0 - 2
Manchester City FC 
|
25 Oktober 2025
| 21:00 |
Valencia CF 
0 - 2
Villarreal CF
|
01 November 2025
| 14:00 |
Villarreal CF
4 - 0
Rayo Vallecano de Madrid 
|
05 November 2025
| 18:45 |
Páfos FC 
1 - 0
Villarreal CF
|
08 November 2025
| 21:00 |
RCD Espanyol de Barcelona 
0 - 2
Villarreal CF
|
22 November 2025
| 21:00 |
Villarreal CF
2 - 1
RCD Mallorca 
|
25 November 2025
| 21:00 |
BV Borussia 09 Dortmund 
4 - 0
Villarreal CF
|
30 November 2025
| 14:00 |
Real Sociedad de Fútbol 
2 - 3
Villarreal CF
|
